Lab 19a Investigating Chemical Equilibrium
Lab 19A: Investigating Chemical Equilibrium
Purpose:
To observe shifts in equilibrium concentrations when stresses such as temperature changes are applied through recognizing macroscopic properties of chemical systems and being able to explain the results using Le Chatelier's principle.
Materials:
Please see page 209 of the “Heath Lab Manual.”
Note: Changes made to the materials/procedure include the optional use of microplates for parts 4 and 5, 250mL Erlenmeyer flasks for parts 1 and 2, 100mL graduated cylindres for part 3, and 10mL graduated cylindres for measuring.
Procedure:
Please see pages 209-212 of the “Heath Lab Manual.”
Note: Changes made to the materials/procedure include the optional use of microplates for parts 4 and 5, 250mL Erlenmeyer flasks for parts 1 and 2, 100mL graduated cylindres for part 3, and 10mL graduated cylindres for measuring.
Data and Observations:
Table #1: Equilibrium Involving Thymol Blue
Reagent added | Stress (ion added) | Colour observation | Directon of equilibrium shift |
HCl (step 3) | |||
HCl (step 4) | |||
NaOH (step 5) | |||
NaOH (step 6) |
Table #2: Equilibrium Involving Thiocyanatoiron (III) Ion
Reagent added | Stress (ion added) | Observation | Direction of equilibrium shift |
KCl (test tube B) | |||
Fe(No3)3 (test tube C) | |||
KSCN (test tube D) | |||
NaOH (test tube E) |
Table #3: Equilibrium Involving Cobalt (II) Complexes
Stress | Observation | Direction of equilibrium shift | |
Step 4 | |||
Step 5 | |||
Step 6 |
Table #4: Equilibrium Involving Chromate and Dichromate Ions
Steps 2 and 3 | 0.1M K2CrO4 | 0.1M K2Cr2O7 | |||
Initial Colour | |||||
1M NaOH added | |||||
1M HCl added | |||||
Step 4 | 0.1M K2CrO4 | 0.1M K2Cr2O7 | |||
Initial Colour | |||||
1M HCl added | |||||
1M NaOH added | |||||
Steps 5 and 6 | Initial Colour | +1M NaOH | +0.1M Ba(NO3)2 | +1M HCl | |
0.1M K2CrO4 | |||||
Steps 7 and 8 | Initial Colour | +1M HCl | +0.1M Ba(NO3)2 | +1M NaOH | |
0.1M K2CrO4 | |||||
Step 9 | 0.1M K2CrO4 | 0.1M K2Cr2O7 | |||
Add 1.0M Ba(NO3)2 |
Table #5: Equilibrium Involving Copper (II) Complexes